They work, but only work well in small, sealed spaces. Most tents are not air tight enough to make a difference so you will probably not get very good results unless you have a well sealed tent.
If you're in a larger space like a room, these bags won't work. I would suggest either bottled CO2 or a CO2 burner. I prefer the CO2 burners, personally, as propane is cheap and easily obtained, and it helps keep my grow room temperatures up in the winter time. This can be an issue in the summertime, though, however, keep in mind that you actually want higher temperatures in your grow space when you are running CO2. Also, paying attention to, and keeping your VPD in the proper threshold is very important when running CO2, otherwise you are throwing money away.