Frankster
Never trust a doctor who's plants have died.
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Ok, I've tried to simplify this for understanding. If you have any questions about concepts, please feel free to ask below.
The formation of humic substances in nature is one of the least understood aspects of humus chemistry and one of the most intriguing. There are three main theories to explain it: the lignin theory of Waksman (1932), the polyphenol theory, and the sugar-amine condensation theory of Maillard (1911). Those theories are insufficient to account for observations in soil research. Humic substances are formed by the microbial degradation of dead plant matter, such as lignin and charcoal.
Humics are important. It's amazing these "coal" like substances actually fuel plant growth, but it's true. There roughly synonymous with broken down organic matter, just the "right size" for re-building what we need. They also act as the the "acid" in a battery, holding energy potential, and capable of assisting in moving ions and minerals, energy chemical exchanges along membrane gradients in solution. They are critical to transpiration, and are likely a major "pipeline' choke point in overall plant metabolism and photosynthesis. They are among the key components driving plant growth. In a nutshell, essentially these "bits of matter" combine with the things like, NPK, Ca+, Mg+, aminios, trace minerals, enzymes, sugars to create fruiting, they get "depleted" in medium or soil over time. Even if your growing hydro, humics have the potential to take your growing up to the next level.
Decomposition products of dead plant materials form intimate associations with minerals, making it difficult to isolate and characterize soil organic constituents
Humic and fulvic acids are chelators. They combine minerals to make them into organic compounds that can be produced into buds more easily. They also enable the soil to hold more water and can increase the water infiltration of the soil.
The operational distinction between humic and fulvic acids. Humin is insoluble in dilute alkali. So-called "gray humic acids" (GHA) are soluble in low-ionic-strength alkaline media; "brown humic acids" (BHA) are soluble in alkaline conditions independent of ionic strength; and fulvic acids (FA) are soluble independent of pH and ionic strength.
A sequential chemical fractionation called Humeomics can be used to isolate more homogeneous humic fractions and determine their molecular structures by advanced spectroscopic and chromatographic methods. Substances identified in humic extracts and directly in soil include mono-, di-, and tri-hydroxy acids, fatty acids, dicarboxylic acids, linear alcohols, phenolic acids, terpenoids, carbohydrates and aminoacids.
These are essentially components in "the stinky" that make buds, THCalkaloids, terpenes, phenols, flavanoids,
typical humic substance is a mixture of many molecules, some of which are based on a motif of aromatic nuclei with phenolic and carboxylic substituents, linked together; the illustration shows a typical structure. The functional groups that contribute most to surface charge and reactivity of humic substances are phenolic and carboxylic groups. Humic acids behave as mixtures of dibasic acids, with a pK1 value around 4 for protonation of carboxyl groups and around 8 for protonation of phenolate groups. There is considerable overall similarity among individual humic acids. For this reason, measured pK values for a given sample are average values relating to the constituent species. The other important characteristic is charge density. The molecules may form a supramolecular structure held together by non-covalent forces, such as van der Waals force, π-π, and CH-π bonds.
The presence of carboxylate and phenolate groups gives the humic acids the ability to form complexes with ions such as Mg2+, Ca2+, Fe2+, and Fe3+. Many humic acids have two or more of these groups arranged so as to enable the formation of chelate complexes.[26] The formation of (chelate) complexes is an important aspect of the biological role of humic acids in regulating bioavailability of metal ions.
side note:
In chemistry, biochemistry, and pharmacology, a dissociation constant ( K d {\displaystyle K_{d}}
) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions. The dissociation constant is the inverse of the association constant. In the special case of salts, the dissociation constant can also be called an ionization constant
The humic extracts are composed of large numbers of different bio-organic molecules that have not yet been totally separated and identified. However, single classes of residual biomolecules have been identified by selective extractions and chemical fractionation, and are represented by alkanoic and hydroxy alkanoic acids, resins, waxes, lignin residues, sugars, and peptides.
What is boils down to, is someone smart enough, can figure out exactly what ratio's of humic extracts (with mass spetrometer) most benefical to bud production, and how to maintain a "loaded amount" or the "maximum feed" of humic substance into the solution at any given time. It's not just about having the right minerals, but also matching up the right ionic charges, or "states" most productive, or in a form that's readily "available" for any chemical reactions to occur. Humics "populate" that ionization on a mass scale. Lining up "charged states" has major advantages (and risks) associated with them.
As you can imagine, lighting your gas tank on fire in your car comes with risk. Same with doing it in a live cell of an organism. But I really believe humics are likely a big driver (and bottleneck) in plant metabolism.
The formation of humic substances in nature is one of the least understood aspects of humus chemistry and one of the most intriguing. There are three main theories to explain it: the lignin theory of Waksman (1932), the polyphenol theory, and the sugar-amine condensation theory of Maillard (1911). Those theories are insufficient to account for observations in soil research. Humic substances are formed by the microbial degradation of dead plant matter, such as lignin and charcoal.
Humics are important. It's amazing these "coal" like substances actually fuel plant growth, but it's true. There roughly synonymous with broken down organic matter, just the "right size" for re-building what we need. They also act as the the "acid" in a battery, holding energy potential, and capable of assisting in moving ions and minerals, energy chemical exchanges along membrane gradients in solution. They are critical to transpiration, and are likely a major "pipeline' choke point in overall plant metabolism and photosynthesis. They are among the key components driving plant growth. In a nutshell, essentially these "bits of matter" combine with the things like, NPK, Ca+, Mg+, aminios, trace minerals, enzymes, sugars to create fruiting, they get "depleted" in medium or soil over time. Even if your growing hydro, humics have the potential to take your growing up to the next level.
Decomposition products of dead plant materials form intimate associations with minerals, making it difficult to isolate and characterize soil organic constituents
Humic and fulvic acids are chelators. They combine minerals to make them into organic compounds that can be produced into buds more easily. They also enable the soil to hold more water and can increase the water infiltration of the soil.
The operational distinction between humic and fulvic acids. Humin is insoluble in dilute alkali. So-called "gray humic acids" (GHA) are soluble in low-ionic-strength alkaline media; "brown humic acids" (BHA) are soluble in alkaline conditions independent of ionic strength; and fulvic acids (FA) are soluble independent of pH and ionic strength.
A sequential chemical fractionation called Humeomics can be used to isolate more homogeneous humic fractions and determine their molecular structures by advanced spectroscopic and chromatographic methods. Substances identified in humic extracts and directly in soil include mono-, di-, and tri-hydroxy acids, fatty acids, dicarboxylic acids, linear alcohols, phenolic acids, terpenoids, carbohydrates and aminoacids.
These are essentially components in "the stinky" that make buds, THCalkaloids, terpenes, phenols, flavanoids,
typical humic substance is a mixture of many molecules, some of which are based on a motif of aromatic nuclei with phenolic and carboxylic substituents, linked together; the illustration shows a typical structure. The functional groups that contribute most to surface charge and reactivity of humic substances are phenolic and carboxylic groups. Humic acids behave as mixtures of dibasic acids, with a pK1 value around 4 for protonation of carboxyl groups and around 8 for protonation of phenolate groups. There is considerable overall similarity among individual humic acids. For this reason, measured pK values for a given sample are average values relating to the constituent species. The other important characteristic is charge density. The molecules may form a supramolecular structure held together by non-covalent forces, such as van der Waals force, π-π, and CH-π bonds.
The presence of carboxylate and phenolate groups gives the humic acids the ability to form complexes with ions such as Mg2+, Ca2+, Fe2+, and Fe3+. Many humic acids have two or more of these groups arranged so as to enable the formation of chelate complexes.[26] The formation of (chelate) complexes is an important aspect of the biological role of humic acids in regulating bioavailability of metal ions.
side note:
In chemistry, biochemistry, and pharmacology, a dissociation constant ( K d {\displaystyle K_{d}}
The humic extracts are composed of large numbers of different bio-organic molecules that have not yet been totally separated and identified. However, single classes of residual biomolecules have been identified by selective extractions and chemical fractionation, and are represented by alkanoic and hydroxy alkanoic acids, resins, waxes, lignin residues, sugars, and peptides.
What is boils down to, is someone smart enough, can figure out exactly what ratio's of humic extracts (with mass spetrometer) most benefical to bud production, and how to maintain a "loaded amount" or the "maximum feed" of humic substance into the solution at any given time. It's not just about having the right minerals, but also matching up the right ionic charges, or "states" most productive, or in a form that's readily "available" for any chemical reactions to occur. Humics "populate" that ionization on a mass scale. Lining up "charged states" has major advantages (and risks) associated with them.
As you can imagine, lighting your gas tank on fire in your car comes with risk. Same with doing it in a live cell of an organism. But I really believe humics are likely a big driver (and bottleneck) in plant metabolism.
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