Advantages of a High CEC
The advantage of a high CEC is not only that the soil or soilless media can hold a lot of fertilizer elements and give them back to plants later, but also it can help buffer or resist a change in pH. For example, if you add limestone to an acidic clay soil, the calcium and magnesium can displace hydrogen (acid ions) from the CEC sites.
The hydrogen bonds with the carbonate coming from the lime, causing an increase in the pH of the clay soil. The more hydrogen ions that are retained by the soil, the more limestone that is needed to adjust the pH of the soil.
Likewise, if fertilizer is applied to a soil, many of these fertilizer elements could bind to the CEC sites; therefore, soils with high CEC require higher fertilizer application rates to compensate for this. Later if fertility levels decline in the soil, some of these fertilizer elements may be exchanged and then become available for plant usage.
Soils and soilless media particles can also have positive charges and this attracts negatively charged particles; these positive sites contribute to the anion exchange capacity of the growing medium. In comparison, the cation exchange capacity is more significant in a soilless media than the anion exchange capacity.
But at the end of the day. CEC matters most in soil grown runs.
https://www.pthorticulture.com/en/training-center/what-is-cec-cation-exchange-capacity/