Water systems here are great all round the country but we're not trying to produce a pure product just a safe one.
You'll notice harder water or more ppm where the catchment area for the rain is on soft rock that readily gives up minerals. Here where I am we get soft water because of all the hard rock which barely weathers over a million years, those on chalk landscapes almost always have harder water.
But this isn't hydro, the soil can hold elements even in different forms as it joins some, these can then later be accessed by the plant. It's all the chemistry which make pH irrelevant, your trying to defeat something composed of millions of ppm with a mere splash of citric acid isn't going to do anything. In fact many ph products aren't desirable for soil and their overuse could just break your buffers down too fast.
Water has a calcium buffer, that carbonate does fancy chemistry with acids. The guy above needs to pH his feed then come back in a day to witness the water buffer it back up.
We can defeat a water buffer easily by reaching the ionisation constant or point all carbonates are used by the acid. This point is about 4.3, slowly pH your water down to pH 4.3 and the second it drops fast past this you've used all your buffer up.
Contrary to belief good soil is in the same range as hydro 5.5-6.5 and rarely will the total volume be one set figure.
Soil tests show the power of the buffer and the amount left rather than give only a pH which can be largely meaningless without all the other info.
A million reasons to keep pH products away from anything soil related, soil manufacturers know exactly how to buffer soil.
If you want to get into the basics of pH and buffers start by reading up about 'strong and weak acids and alkalis' and 'alkalinity Vs pH' but do not pH soil or any soil products ever. Were more the type to shit in a shell, bury it in the garden for a year then dig it up and marvel at the amazing fertilizer we just created for free