No worries, this gal actually prefers something called the slurry method.
You take samples from all the pots, mix those up.
You add those to RO or distilled water, after you've measured its pH and EC parameters (you're more concerned that it's a 0EC than a particular pH here).
Mix in enough of the coir samples to create a slurry, then let sit for 7-10 minutes. I have not found that letting the samples sit longer changes the readings after 10minutes, it stays the same.
Now, measure the pH and EC. What you read there is an excellent picture of what's going on *in* the root zone, instead of what's coming out of the root zone. This, of course, is why it's important to get more than one sample and from more than one level or area of the media. I'll upend the pots and scrape some off the sides and bottom, and then I'll take a little chunk out of the middle. Again, be *sure* it's all well mixed together.
If you have some plants that are showing an issue and others aren't, then do this test separating the media by those that are performing well and those that aren't. If they're showing different issues, separate by issue.
Good diagnosis, it's a Ca-, classic. You're gonna be playing a little catch-up here now. Got a Ca-only product to use here?