I didn't read this whole thread but just fyi, you don't supplement co2 during the dark period. Lights on only. So if you are using it during the dark period, it's a waste.
As far as danger, eh...almost everything is dangerous if you don't know what you are doing. People use dry ice all the time without dying, there's no real reason the OP couldn't be one of those people. I didn't see any co2 numbers though. What was your starting co2 level and after the dry ice? However...
The dry ice route isn't cost effective, even if you have a guy. My last flower space was 6' x 11' x 7', and to replenish co2 to 1200 ppm every hour during lights on cost me $40-$60 a month, it varies depending on plant size. I mean you need a regulator, timer, etc, but it's by far the easier and cheaper route.
Also, imo, the co2 needs to be for the entire 12/12 cycle. What we are doing is raising the plants metabolism. Bumping it up a few times a week...on paper, it's good, it's better. But the gains will be slight and probably not super noticeable.
To give you an analogy, it's like if you ate a clean diet every day, and exercised appropriately. That raises your metabolic rate in a way that will be noticeable. Assuming you are healthy, you burn more calories, your energy will be higher, weight loss, etc. Eating clean one or two meals a week and exercising sporadically, isn't going to raise your metabolic rate in a way that is very noticeable. To really reap the benefits of Co2, it needs to be a "constant", not occasional, to be worth the effort.
All imo and a fair amount of ime.