You need to figure out the cubic footage of your grow area, the CO2 output of your unit, and then it's some pretty easy math (ignoring CO2 uptake differences between plants, which is kinda big to ignore, IMO).
Or buy an atmospheric controller and set it and forget it.
I'd pick "B", but it's your call.
And as far as whether or not to run it in veg, that's your call - but you're certainly going to be running it for flowering.
And only run it when the lights are on in flowering - plants don't need it at night.