There's a huge range of options when it comes to greenhouse efficiency. Fortunately the commercial gh industry has been around forever and has gotten pretty advanced at this. Most popular options:
-insulate around the perimeter of the greenhouse underground (prevents frost creep into the soil; maintains warmer soil temperatures which then serves to stabilize the gh temp)
-integrate thermal mass - usually water barrels. check out the blog at
ceresgs.com. Just saw they have a good article on water barrels for greenhouses there.
-add a second layer of glazing
-insulate your glazing if possible
-a more insulating light dep / shade cloth curtian that closes at night
Those are a few..."The Year Round Solar Greenhouse" is a good book if looking at the range of options for sustainable heating / cooling.