This is why I need to get some lysimeters and a quality scope. :)
What brand probe do you use? I've considered it, the
bluelab one looks promising as ph and ec pens I have from them work quite well. You're absolutely right about the runoff ph being unreliable but I feel if it is inconsistent with what I'm used to it can be a flag to run some further tests. I've done slurrys in the past but I'm experimenting with coco, running it like rockwool in small amounts, so any digging I do will result in disturbing the root mass more than I am comfortable with.
So, my medium ph appears to be back on track, under feeding was definitely a contributing factor. Though my Rez clouded up on me again after a couple days, I'm thinking it's the fulvic acid falling out, as it's the only organic part of my fertigation regiment.
A different resevoir for a different room has had the b. Amylo added for a month straight now and the ph in there is just fine, so maybe I jumped the gun, but there's too many mitigating factors to say for sure.
You can use the biotic ligand model to study aquatic toxicity I think buddy, perhaps someone like
@Seamaiden can provide some assistance or have some input. Being a fishkeeper, she may well be versed in the practice. I know we test free metal ion concentrations in the nutrient solutions using the Donnan membrane technique and labile metal concentrations by diffusive gradients in thin-films.
Just wild input based on our short discussion....
Depending on your water source, media type and so metal/ organic matter, acids such as fulvic may be putting metals in to a more leachable state. You may simply be noticing a drop out of Fe, Cu or other dropping out your pH at run off, of course over time this will stabilise but you may well have drifted out some more valued metals in sediment or gas etc.
You need to be careful since this certainly would mean unwanted metals (Cd Pb etc) are more likely being taken up at the roots, and whats in the roots, is for sure as day follows night, in the shoots.
There is a wide range of hugely conflicting data regarding the additions of humates via acids humic or fulvic, and any such study is typically studied in odd situations with a very narrow focus, which tends not to include the soil as a system, eg where in nature we have many fungal strains acting as a land reef, and barrier, so assisting plants by pre screening pollutants, many of which are toxic metals and petrols for example. Any paper I read about humic acid and its phytotox potential for plants, its usually completed in systems where no case is made for wider participation.
FYI: BOX are currently in the early stages of our own studies, which have combined the research and so skill of both elemental soil scientists, micro biologists, experts in bacteria, fungus and the soil food web. We have included some wider study via geologists and water experts chiming in to give us a far wider image of whats really happening in systems where pollutants are highly probable. Its a live in field and controlled glass house study here in Esti and in locations across the UK, Spain and Poland. At no point soon will i be able to give you any data, we have reports due across the year, but the paper itself is someway off.
As a rule, I use humic acids in soil less media types, i tend not to use them where i have higher biology and organics, since the organics and biology make the stuff for me, no sense over egging the lot and tipping the balance imo.
I sell humates too mate, but I try to be honest about the extent of our understanding. There is no question humates can help to repair damage done to soil systems and they can therefore assist our plants in the uptake of many good elements. Where papers claim we may leach Fe with its use, esp in higher doses, I would argue bacillus subtilus and many other ferro bacterium will gladly scoop up that leaching Fe and the mycos would trap and leaching Cu recycling it via the SFW. We will see in time who is right and who just wrote a paper that in typical academic style, contains very little usable information. :-)